The First Atmosphere

Ι have now published the second edition of my ebook “Planetary Formation and Biogenesis”. It has just under 1290 references, each about a different aspect of the issue, although there is almost certainly a little double counting because references follow chapters, and there will be some scientific papers that are of sufficient importance to be mentioned in two chapters. Nevertheless, there is plenty of material there. The reason for a second edition is that there has been quite a lot of additional; information from the past decade. And, of course, no sooner did I publish than something else came out, so I am going to mention that in this post. In part this is because it exemplifies some of what I think is wrong with modern science. The paper, for those interested, is from Wilcoski et al. Planet Sci J. 3: 99. It is open access so you can read it.

First, the problem it attempts to address: the standard paradigm is that Earth’s atmosphere was initially oxidised, and comprised carbon dioxide and nitrogen. The question then is, when did this eventuate? What we know is the Earth was big enough that if still in the accretion disk it would have had an atmosphere of hydrogen and helium. If it did not accrete until after the disk was expelled, it would have no atmosphere initially, and an atmosphere had to come from some other process. The ebook shows the evidence and in my opinion it probably had the atmosphere of hydrogen. Either way, the accretion disk gets expelled, and assuming our star was the same as others, for the first few hundred million years the star gave off a lot of extremely energetic UV radiation, and that would be sufficient to effectively blow any atmosphere away. So under that scenario, for some number of hundred million years there would be no atmosphere.

There is an opposing option. Shortly after the Moon-forming event, there would be a “Great Bombardment” of massive impactors. There are various theories this would form a magma ocean and there is a huge steam atmosphere, but there is surprisingly little evidence for this, which many hold onto no matter what. The one piece of definite evidence are some zircons from the Jack Hills in Australia, and these are about 4.2 – 4.3 billion years old – the oldest of any rock we have. Some of these zircons show clear evidence that they formed under temperatures not that different from today. In particular, there was water that had oxygen isotope ratios expected of water that had come from rain.

So, let me revisit this paper. The basic concept is that the Earth was bombarded with massive asteroids and the iron core hit the magma ocean, about half of it was sent into the atmosphere (iron boils at 2861 degrees C) where it reacted with water to form hydrogen and ferrous oxide. The hydrogen reacted with nitrogen to form ammonia.

So, what is wrong with that? First, others argue that iron in the magma ocean settles to the core. That, according to them, is why we have a core. Alternatively, others argue if it comes from an asteroid, it emulsifies in the magma. Now we have the iron doing three different kind of things depending on what answer you want. It can do one of them, but not all of them. Should iron vapour get into the atmosphere, it would certainly reduce steam and make hydrogen, but then the hydrogen would not do very much, but rather would be lost to space because of the sun’s UV. The reaction of hydrogen with nitrogen only proceeds to make much ammonia when there is intense pressure. That could happen deep underground. However, in atmospheric pressure at temperatures above the boiling point of iron, ammonia would immediately dissociate and form nitrogen and hydrogen. The next thing that is wrong is that very few asteroids have an iron core. If one did, what would happen to the asteroid when it hit magma? As an experiment, throw ice into water and watch what happens before it tries to reverse its momentum and float (which an asteroid would not do). Basically, the liquid is what gets splashed away. Rock is a very poor conductor of heat, so the asteroid will sink quite deeply into the liquid and will have to melt off the silicates before the iron starts to melt, and then, being denser, it will sink to the core. On top of that it was assumed the atmosphere contained 100 bars of carbon dioxide, and two bars of nitrogen, in other words an atmosphere somewhat similar to that of Venus today. Assuming what was there to get the answer you want is, I suppose, one way of going about things, in a circular sort of way. However, with tidal heating from a very close Moon, such an atmosphere with that much water would never rain, which contradicts the zircon data. What we have is a story that contradicts the very limited physical evidence we have, which has no evidence in favour of it, and was made up to get the answer wanted so they could explain where the chemicals that formed life might have come from. Needless to say, my ebook has a much better account, and has the advantage that no observations contradict it.